Scope and limitations of a novel synthesis of 3-arylazonicotinates.
نویسندگان
چکیده
The reaction of 3-oxo-3-phenyl-2-phenylhydrazonal with functionally substituted and heteroaromatic substituted acetonitrile to yield arylazonicotinic acid derivatives and 5-arylsubstituted pyridines was established. In some cases the produced nicotinates could not be isolated as they underwent thermally induced 6π-electrocyclization yielding polynuclear pyridine derivatives.
منابع مشابه
Enzymatic Synthesis of Sucrose-6-acetate by a Novel Immobilized Fructosyltransferase From Aspergillus sp. GX-0010
Background: Sucralose is an ideal food sweetener and sucrose-6-acetate (s-6-a) is a key intermediate for synthesis of sucralose. Synthesis of s-6-a was studied by free fructosyltransferase (FTase) from Aspergillus oryzae. Because of the limitations of free enzyme in stability and reusability, a FTase obtained from the new isolated Aspergillus sp. GX-0010 was immobilized and inv...
متن کاملEfficient synthesis of xanthene derivatives in aqueous media in the presence of Cu-anchored furfural imine-functionalized halloysite
A novel hybrid catalyst based on grafting Cu on furfural imine-functionalized halloysite was designed, characterized and used for promoting synthesis of xanthene derivatives via three- component reaction of benzaldehyde derivatives, dimedone, and β-naphthol in aqueous media and under mild reaction condition. The results established high catalytic activity of the hybrid system, which was superio...
متن کاملEfficient synthesis of xanthene derivatives in aqueous media in the presence of Cu-anchored furfural imine-functionalized halloysite
A novel hybrid catalyst based on grafting Cu on furfural imine-functionalized halloysite was designed, characterized and used for promoting synthesis of xanthene derivatives via three- component reaction of benzaldehyde derivatives, dimedone, and β-naphthol in aqueous media and under mild reaction condition. The results established high catalytic activity of the hybrid system, which was superio...
متن کاملFabrication of PGS/CaTiO3 Nano-Composite for Biomedical Application
Biodegradable elastomeric materials are gaining extensive attention in the field of soft tissue engineering. Poly (glycerol sebacate) (PGS) is a novel biocompatible elastomer in this scope. However this polymer has poor mechanical properties especially when the molar ratio of glycerol is higher than sebacic acid. Calcium Titanate (CaTiO3) is a biocompatible ceramic with some degr...
متن کاملA Novel and Efficient Synthesis of New Dixanthones
The facile and high yield synthesis of a new series of dibenzophenones in the presence of polyphosphoric acid (PPA) together with their cyclization to corresponding moni and dixanthones are described. The aromatic nucleophilic substitution of these new compounds are also studied.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Molecules
دوره 17 5 شماره
صفحات -
تاریخ انتشار 2012